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The colors of rubies and emeralds are so striking that they define shades of red and green – ruby red and emerald green. But have you ever wondered how they get those colors?
I am an inorganic chemist. Researchers in my field work to understand the chemistry of all the elements that make up the periodic table. Many focus on the transition metals – the elements in the middle of the periodic table. The most of the metals you are familiar with, like iron (Fe) and gold (Au).
One feature of compounds made with transition metals is their intense color. There are many examples in nature, including gemstones and paint pigments. Even the color of blood comes from the , which contains iron.
Investigating the colors of compounds containing transition metals leads you into some really amazing science – that ºÚÁÏÉçÇø. part of what drew me to study this field.
and are great examples of how a small amount of a transition metal – in this case, – can create a beautiful color in what would otherwise be a fairly boring-looking mineral.
Minerals and crystals
Both rubies and emeralds are with a consistent chemical composition and a highly ordered structure at the atomic level.
When this highly ordered structure extends in all three dimensions, .
With called crystal field theory, scientists can explain why rubies and emeralds have the colors they do. Crystal field theory makes predictions about how a transition metal ion ºÚÁÏÉçÇø. structure is affected by the other atoms surrounding it.
Rubies are mainly made up of , which is composed of the elements aluminum and oxygen in a regular, repeating array. Each is surrounded by six oxygen ions.
Emeralds are mainly made up of , which is made from the elements beryllium, aluminum, silicon and oxygen. Beryl ºÚÁÏÉçÇø. crystal structure is more complicated than corundum ºÚÁÏÉçÇø. because of the additional elements in the formula, but each aluminum ion is again surrounded by six oxygen ions.
Pure corundum and beryl are colorless. The brilliant colors of rubies and emeralds come from the presence of very small amounts of . The chromium replaces about 1% of the aluminum in the corundum or beryl crystal when a ruby or emerald forms underground at a high temperature and pressure.
But how can one element – chromium – create the red color of a ruby and green color of an emerald?
Color science
Rubies and emeralds have the colors they do because, like many substances, they absorb some colors of light. Most visible light, like sunlight, is composed of all the colors of the rainbow: red, orange, yellow, green, blue, indigo and violet. These colors make up the , which is easy to remember as ROY G BIV.
(Objects absorb some visible light wavelengths and reflect others, which is why we see them as having a color. , )
One of the main reasons why is because they absorb one or more of these visible colors of light. If a substance absorbs, for instance, red light, it means that the red light gets trapped in the substance and the other colors reflect back to your eyes. The color you see is the sum of the remaining light, which will be in the green-to-blue range. If a substance absorbs blue, it will look red or orange to you.
Unlike the colorless aluminum ion, the chromium ion absorbs blue and green light when surrounded by the oxygen ions. The red light is reflected back, so that ºÚÁÏÉçÇø. what you see in rubies.
In an emerald, even though the chromium is surrounded by six oxygen ions, there is a weaker interaction between the chromium and the surrounding oxygen ions. That ºÚÁÏÉçÇø. due to the presence of silicon and beryllium in the beryl crystal. They cause the emerald to absorb blue and red light, leaving the green for you to see.
The ability to tune the properties of transition metals like chromium through changing what is surrounding it is a core strategy in my field of inorganic chemistry. Doing so can help scientists understand the basic science of metal-containing compounds and the design of chemical compounds for specific purposes.
You can take delight in the amazing colors of the gemstones, but through chemistry, you can also see how nature creates those colors using an endless variety of complex structures made with the elements in the periodic table.
